Isolation and identification of odorants generated in wine during its oxidation: a gas chromatography-olfactometric study

被引:98
作者
Escudero, A [1 ]
Cacho, J [1 ]
Ferreira, V [1 ]
机构
[1] Univ Zaragoza, Fac Sci, Dept Analyt Chem, E-50009 Zaragoza, Spain
关键词
wine; flavor; oxidation; aroma; gas chromatography-olfactometry;
D O I
10.1007/s002179900128
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
The changes in the flavor profiles of several white wines undergoing oxidation were monitored through gas chromatography-olfactometry (GCO). The study showed that up to 19 odorants were generated during wine oxidation. and that several of the odorants originally present in the wine disappeared or decreased. An aroma extract dilution analysis revealed that 5 of these 19 odorants have maximum dilution factors, and that a second group of 7 may have some sensory significance as well. The isolation and identification of the different odorants was achieved via normal and reverse-phase high-performance liquid chromatography and high-resolution GCO. The impact odorants of oxidized wine were found to be 2, 4, 5-trimethyldioxolane, methional (methylthioproganal), sotolon (4,5-dimethyl-3-hydroxy-2(5H) -furanone), eugenol (4-propenyl-2-methoxyphenol) and an unknown compound with mass spectrum similar to methylvanillate. Other odorants also formed during wine oxidation were 1-octen-3-ol, t-2-nonenal, furfural, benzaldehyde, 2-butoxyethanol, acetovanillone and a dioxolane isomer.
引用
收藏
页码:105 / 110
页数:6
相关论文
共 33 条
[11]   Changes in the profile of volatile compounds in wines stored under oxygen and their relationship with the browning process [J].
Ferreira, V ;
Escudero, A ;
Fernandez, P ;
Cacho, JF .
ZEITSCHRIFT FUR LEBENSMITTEL-UNTERSUCHUNG UND-FORSCHUNG A-FOOD RESEARCH AND TECHNOLOGY, 1997, 205 (05) :392-396
[12]  
FERREIRA V, IN PRESS J CHROMATOG
[13]  
FERREIRA V, 1993, PROGR FOOD FERMENTAT, V2, P449
[14]   ENANTIOMERIC RATIOS OF PANTOLACTONE, SOLERONE, 4-CARBOETHOXY-4-HYDROXY-BUTYROLACTONE AND OF SOTOLON, A FLAVOR IMPACT COMPOUND OF FLOR-SHERRY AND BOTRYTIZED WINES [J].
GUICHARD, E ;
ETIEVANT, P ;
HENRY, R ;
MOSANDL, A .
ZEITSCHRIFT FUR LEBENSMITTEL-UNTERSUCHUNG UND-FORSCHUNG, 1992, 195 (06) :540-544
[15]  
Lavigne Valerie, 1992, Journal International des Sciences de la Vigne et du Vin, V26, P75
[16]   THE STABILITY OF FLAVOR CONSTITUENTS IN ALCOHOLIC BEVERAGES [J].
LAWS, DRJ ;
PEPPARD, TL .
FOOD CHEMISTRY, 1982, 9 (1-2) :131-146
[17]  
Markl K. S., 1987, Technical Quarterly, Master Brewers' Association of the Americas, V24, P9
[18]   MORE CLUES ABOUT SENSORY IMPACT OF SOTOLON IN SOME FLOR SHERRY WINES [J].
MARTIN, B ;
ETIEVANT, PX ;
LEQUERE, JL ;
SCHLICH, P .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1992, 40 (03) :475-478
[19]   Fishy and hay-like off flavours of dry spinach [J].
Masanetz, C ;
Guth, H ;
Grosch, W .
ZEITSCHRIFT FUR LEBENSMITTEL-UNTERSUCHUNG UND-FORSCHUNG A-FOOD RESEARCH AND TECHNOLOGY, 1998, 206 (02) :108-113
[20]   Identification and quantification of potent odorants in regular fat and low-fat mild cheddar cheese [J].
Milo, C ;
Reineccius, GA .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1997, 45 (09) :3590-3594