SYNTHESIS OF RARE SUGARS

被引：58

作者：

BRIMACOMBE, JS

机构：

[1] Department of Chemistry, University of Birmingham, Birmingham, PO Box 363, Edgbaston

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1969年 / 8卷 / 06期

关键词：

Carbohydrates;

D O I：

10.1002/anie.196904011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of new oxidation reagents, such as the Pfitzner‐Moffatt reagent, dimethyl sulfoxide‐acid anhydrides, and ruthenium tetroxide, has significantly improved the yields obtained on oxidation of a secondary hydroxyl group to a carbonyl group in suitably protected sugars. The application of these new oxidants in the carbohydrate field is briefly surveyed. The product ketones are convenient intermediates for syntheses of amino, branched‐chain, deoxy, and other rare sugars. Some representative syntheses are illustrated. Copyright © 1969 by Verlag Chemie, GmbH, Germany

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页码：401 / +

页数：1

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