X-RAY STRUCTURE OF A SELF-ASSEMBLED GELATING FIBER

被引：96

作者：

MENGER, FM

YAMASAKI, Y

CATLIN, KK

NISHIMI, T

机构：

[1] Department of Chemistry, Emory University, Atlanta, Georgia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 05期

关键词：

CYSTINE; GELS; SELF-ASSEMBLY; STRUCTURE ELUCIDATION;

D O I：

10.1002/anie.199505851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The relationship between the properties and structure of gels has never been properly elucidated because of the lack of structural information. Now the X‐ray structure of the gel‐forming acylcystine (1)–the first of such a molecule at atomic resolution–has been successfully performed. The fibers of 1 are stabilized by the backbone orientation, as well as by hydrogen bonding and π–π stacking interactions, while the individual strands are linked by hydrogen bonding. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：585 / 586

页数：2

共 15 条

[1] COLLAGEN - MOLECULAR DIVERSITY IN THE BODYS PROTEIN SCAFFOLD [J].