CHEMICAL LITHIUM EXTRACTION FROM MANGANESE OXIDES FOR LITHIUM RECHARGEABLE BATTERIES

被引：35

作者：

LUBIN, F ^{[1
]}

LECERF, A ^{[1
]}

BROUSSELY, M ^{[1
]}

LABAT, J ^{[1
]}

机构：

[1] SAFT,F-86060 POITIERS,FRANCE

来源：

JOURNAL OF POWER SOURCES | 1991年 / 34卷 / 02期

关键词：

D O I：

10.1016/0378-7753(91)85036-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chemical lithium extraction has been carried out on the following manganese oxides: the spinel-type compounds LiMn2O4 and Li4/3Mn5/3O4, and the rocksalt-related compound Li2MnO3. Lithium can be partially removed chemically from these compounds without destroying the host framework. Some compounds obtained by this method have been tested as cathodic materials in rechargeable lithium cells. Electrochemical results and X-ray diffraction patterns of cycled cathodes are presented. Electrochemical insertion/extraction of Li+ ions occurs with tetragonal/cubic distortion in the spinel framework, whereas Li+ ions can move in compounds having the rocksalt structure, without significant modification of the X-ray patterns.

引用

页码：161 / 173

页数：13

共 15 条

[11] ELECTROCHEMISTRY OF MANGANESE-DIOXIDE IN LITHIUM NONAQUEOUS CELL .3. X-RAY DIFFRACTIONAL STUDY ON THE REDUCTION OF SPINEL-RELATED MANGANESE-DIOXIDE [J].