Validation of OMI tropospheric NO2 observations during INTEX-B and application to constrain NOx emissions over the eastern United States and Mexico

We compare tropospheric NO, column measurements from the Ozone Monitoring Instrument (OMI) aboard the EOS Aura satellite with coincident in situ aircraft measurements on vertical spirals over the southern United States, Mexico, and the Gulf of Mexico during the INTEX-B campaign in March 2006. Good correlation with no significant bias (r(2) = 0.67, slope = 0.99 +/- 0.17, n = 12) is found for the ensemble of comparisons when the aircraft could spiral sufficiently low to sample most of the NO, column. Urban spirals where large extrapolations were needed below the aircraft floor (1000ft) showed poorer agreement. We use the OMI observations together with a global chemical transport model (GEOS-Chem) to estimate emissions of nitrogen oxides over the eastern United States and Mexico in March 2006. Comparison to EPA's National Emissions Inventory 1999 (NE199) calls for a decrease in power plant emissions and an increase in on-road vehicle emissions relative to that inventory. The rise in vehicular emissions is offsetting the reduction in power plant and industry emissions. These findings are consistent with independent assessments. Our OMI-derived emission estimates for Mexico are higher by a factor of 2.0 +/- 0.5 than bottom-up emissions, similar to a comparison between the recently released Mexican NE199 inventory and the bottom-up showing that the Mexican NE199 inventory is 1.6-1.8x higher. (C) 2008 Elsevier Ltd. All rights reserved.