VIBRATION SPECTRA AND NORMAL COORDINATE ANALYSIS OF SOME HEXAHALODISILAZANES AND HEXAHALODISILOXANES

被引：25

作者：

BURGER, H

BURCZYK, K

HOFLER, F

SAWODNY, W

机构：

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 12期

关键词：

D O I：

10.1016/0584-8539(69)80220-5

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The infrared and Baman spectra of (Cl3Si)2NH, (Cl3Si)2ND, (Cl3Si)2O, (Br3Si)2NH, and (Br3Si)2O are reported. A normal co-ordinate analysis using a transferable MVFF to fit the spectra of all molecules has been performed. The SiN and SiO stretching force constants were calculated to be 4·5 and 5·4 for the hexachloro- and 4·3 and 6·1 for the hexabromo compounds. © 1969.

引用

页码：1891 / &