A B-RING CONTRACTED SPIROSTANE FROM TACCA-LEONTOPETALOIDES

被引:9
作者
ABDELAZIZ, A
BRAIN, K
SHATALEBI, MA
BLUNDEN, G
PATEL, A
CRABB, TA
BASHIR, AK
机构
[1] UNIV WALES COLL CARDIFF,WELSH SCH PHARM,CARDIFF CF1 3XF,WALES
[2] PORTSMOUTH POLYTECH,DEPT CHEM,PORTSMOUTH PO1 2DZ,HANTS,ENGLAND
[3] NATL COUNCIL RES,KHARTOUM,SUDAN
关键词
(25R)-B-nor(7)-6β-formylspirostane-3β; 5β-diol; B-ring contracted spirostane; steroidal sapogenin; Tacca leontopetaloides; Taccaceae;
D O I
10.1016/0031-9422(90)85200-Y
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Leontogenin, 25(R)-B-nor(7)-6β-formyl-spirostane-3β,5β-diol, was isolated from the acid hydrolysate of an extract of leaves of Tacca leontopetaloides and its structure elucidated from IR, 1H and 13C NMR spectroscopic and mass spectrometric data. This is the first report of a naturally occurring spirostane showing B-ring contraction. The possible origin of this compound is discussed. © 1990.
引用
收藏
页码:2623 / 2627
页数:5
相关论文
共 15 条
[1]  
ABADI MAS, 1988, THESIS U WALES
[2]  
ABDELAZIZ A, 1990, IN PRESS PLANTA MED
[3]  
ABDELAZIZ A, 1990, IN PRESS PHYTOCHEMIS, V29
[4]  
ABDELAZIZ A, 1988, THESIS U WALES
[5]   C-13 NMR SPECTRAL INVESTIGATIONS .10. C-13 NMR-SPECTROSCOPY OF STEROIDAL SAPOGENINS AND STEROIDAL SAPONINS [J].
AGRAWAL, PK ;
JAIN, DC ;
GUPTA, RK ;
THAKUR, RS .
PHYTOCHEMISTRY, 1985, 24 (11) :2479-2496
[6]  
[Anonymous], 1965, CONFORMATIONAL ANAL
[7]   ISOLATION AND STRUCTURE OF AN A-RING CONTRACTED TRITERPENOID FROM COLUBRINA-TEXENSIS TISSUE-CULTURE [J].
BAXTER, RL ;
WALKINSHAW, MD .
PHYTOCHEMISTRY, 1988, 27 (07) :2350-2352
[8]   C-13 NMR-STUDIES .69. C-13 NMR-SPECTRA OF STEROIDS - SURVEY AND COMMENTARY [J].
BLUNT, JW ;
STOTHERS, JB .
ORGANIC MAGNETIC RESONANCE, 1977, 9 (08) :439-464
[9]   C-13 NMR-STUDIES OF 5-ALPHA-CHOLESTAN-5-OLS AND 5-BETA-CHOLESTAN-5-OLS AND ANALOGOUS 8A-METHYL-TRANS AND CIS-DECAHYDRONAPHTHALEN-4A-OLS [J].
COXON, JM ;
GIBSON, JR .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1981, 34 (07) :1451-1465
[10]   MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .194. MASS SPECTROMETRIC FRAGMENTATIONS OF STEROIDAL SAPOGENINS [J].
FAUL, WH ;
DJERASSI, C .
ORGANIC MASS SPECTROMETRY, 1970, 3 (09) :1187-&