BIMOLECULAR DECAY OF ALPHA-HYDROXYMETHYLPEROXYL RADICALS IN AQUEOUS-SOLUTION

被引：68

作者：

BOTHE, E ^{[1
]}

SCHULTEFROHLINDE, D ^{[1
]}

机构：

[1] MAX PLANCK INST COAL RES,INST STRAHLENCHEM,STIFT STR 3436,D-4330 MULHEIM,FED REP GER

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1978年 / 33卷 / 07期

关键词：

D O I：

10.1515/znb-1978-0720

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bimolecular decay of the hydroxymethylperoxyl radical in aqueous solution (k = 2.1 X 109 M-1s-1) leads mainly (80%) to one molecule of hydrogen peroxid and to two molecules of formic acid. 2 HOCH2OO ← H2O2 + 2 HCOOH Deuterium kinetic isotope effects show that the decay occurs at room temperature via a short lived (τ < 10-4 s) tetroxid. © 1978, Walter de Gruyter. All rights reserved.

引用

页码：786 / 788

页数：3

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