MICROWAVE AND RADIO-FREQUENCY SPECTRUM OF XEHCL

被引：47

作者：

CHANCE, KV ^{[1
]}

BOWEN, KH ^{[1
]}

WINN, JS ^{[1
]}

KLEMPERER, W ^{[1
]}

机构：

[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 11期

关键词：

D O I：

10.1063/1.437356

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Microwave and radio frequency spectra of 132XeH35Cl are measured by molecular beam electric resonance spectroscopy. The spectroscopic constants determined for this complex are B=989.262 (5) Mhz, DJ=3.84 (32) kHz, (eqQ)a 35Cl=-34.640 (20) MHz, μa=1.0901 (30) D. Only a single vibrational level, with zero angular momentum along the heavy atom axis, has been observed. The results are interpreted in terms of a linear complex with large amplitude oscillation. The structure is assumed to have atomic arrangement XeHCl. The average Xe-Cl distance is 4.258 Å. The average angle of the HCl subunit with the heavy atom axis is 34.8°. The stretching frequency of the weak bond is 33.5 cm-1. © 1979 American Institute of Physics.

引用

页码：5157 / 5160

页数：4

共 19 条

[1]

BOWEN KH, 1977, THESIS HARVARD U

[2] THERMODYNAMICS OF LIQUID-MIXTURES OF XENON AND HYDROGEN-CHLORIDE [J].