NICKEL CATALYZED ASYMMETRIC CROSS-COUPLING REACTION BETWEEN C6H5X AND S-BUMGX - INFLUENCE OF THE NATURE OF THE HALOGENS OF THE 2 REAGENTS

被引：20

作者：

CONSIGLIO, G ^{[1
]}

PICCOLO, O ^{[1
]}

机构：

[1] UNIV PADUA,CNR,IST CHIM ANAL,CTR STUDIO STABILITA & REATTIVITA COMPOSTI COORDINAZIONE,I-35100 PADUA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 177卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94089-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The asymmetric cross-coupling reaction between phenyl halides and sec-butyl-magnesium halides has been carried out in the presence of [(+)(R-1,2-bis(diphenylphosphino)propane]nickel(II) chloride. The optical purity and the absolute configuration of the 2-phenylbutane were dependent on which halogen was present in the organic and the organometallic moieties. © 1979.

引用

页码：C13 / C15

页数：3

共 10 条

[1] STEREOSELECTIVE FORMATION OF C-C BOND IN COUPLING REACTION BETWEEN SECONDARY ALKYLMAGNESIUM BROMIDES AND UNSATURATED HALIDES - ASYMMETRICAL INDUCTION BY OPTICALLY-ACTIVE DIPHOSPHINE NICKEL-COMPLEX [J].

CONSIGLIO, G ;

BOTTEGHI, C .

HELVETICA CHIMICA ACTA, 1973, 56 (01) :460-463

[2] ASYMMETRIC SYNTHESIS - ASYMMETRIC HOMOGENEOUS HYDROGENATION CATALYST WHICH BREEDS ITS OWN CHIRALITY [J].

FRYZUK, MD ;

BOSNICH, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (17) :5491-5494

[3] HIGH STEREOSELECTIVITY IN ASYMMETRIC GRIGNARD CROSS-COUPLING CATALYZED BY NICKEL-COMPLEXES OF CHIRAL(AMINOALKYLFERROCENYL)PHOSPHINES [J].

HAYASHI, T ;

TAJIKA, M ;

TAMAO, K ;

KUMADA, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (12) :3718-3719

[4] DITERTIARY ARSINE AND PHOSPHINE COMPOUNDS OF NICKEL(2) PALLADIUM(2) AND PLATINUM(2) [J].

HUDSON, MJ ;

NYHOLM, RS ;

STIDDARD, MH .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (01) :40-&

[5]

IZUMI Y, 1977, STEREODIFFERENTIATIN

[6]

KISO Y, 1974, TETRAHEDRON LETT, P3

[7]

KOCHI JK, 1978, ORGANOMETALLIC MECHA, P393

[8]

LARDICCI L, 1970, ATTI SOC TOSCANA S A, V77, P25

[9]

TAMAO K, 1973, J ORGANOMET CHEM, V55, pC91, DOI 10.1016/S0022-328X(00)82058-6

[10] ALKYL GROUP ISOMERIZATION IN CROSS-COUPLING REACTION OF SECONDARY ALKYL GRIGNARD-REAGENTS WITH ORGANIC HALIDES IN PRESENCE OF NICKEL-PHOSPHINE COMPLEXES AS CATALYSTS [J].

TAMAO, K ;

KISO, Y ;

SUMITANI, K ;

KUMADA, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (26) :9268-9269

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