Retention and inversion in bimolecular substitution reactions of methane

被引：77

作者：

Van der Lugt, W. Th. A. M. ^{[1
]}

Ros, P. ^{[1
]}

机构：

[1] Shell Res NV, Koninklijke Shell Lab, Amsterdam, Netherlands

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 4卷 / 06期

关键词：

D O I：

10.1016/0009-2614(69)80271-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Non-empirical calculations on the geometry of the CH5+ and CH5- ions are reported. From the results it can be concluded that bimolecular nucleophilic and electrophilic substitution reactions at a saturated carbon atom proceed with inversion and retention of configuration, respectively.

引用

页码：389 / 392

页数：4

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