THEORETICAL INTERPRETATION OF THE STABILITY OF ANOMALOUSLY SMALL DOUBLY CHARGED PARADIFLUOROBENZENE CLUSTERS

被引：14

作者：

BRENNER, V ^{[1
]}

MARTRENCHARD, S ^{[1
]}

MILLIE, P ^{[1
]}

JOUVET, C ^{[1
]}

LARDEUXDEDONDER, C ^{[1
]}

SOLGADI, D ^{[1
]}

机构：

[1] UNIV PARIS 11, CNRS, PHOTOPHYS MOLEC LAB, F-91405 ORSAY, FRANCE

来源：

CHEMICAL PHYSICS | 1992年 / 162卷 / 2-3期

关键词：

D O I：

10.1016/0301-0104(92)85008-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The stability of small doubly charged (paradifluorobenzene)n greater-than-or-equal-to 3(2+) clusters produced in a supersonic expansion by multiphoton ionization can be explained by calculations taking into account intermolecular interactions between neutral and ionic species without involving any change of their chemical nature. The variation of the critical size of appearance for doubly charged paradifluorobenzene and benzene clusters can be explained by the differences in intermolecular potentials and by the formation process.

引用

页码：303 / 320

页数：18

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