SYNTHESES OF (-)-ALPHA-AND (+)-BETA-CIS-BERGAMOTENES

被引：77

作者：

GIBSON, TW

ERMAN, WF

机构：

[1] Procter, Gamble Company, Miami Valley Laboratories, Cincinnati

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 17期

关键词：

D O I：

10.1021/ja01045a032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syntheses of (–)-α-cis-bergamotene (2) and (+)-β-cis-bergamotene (3) from (–)-β-pinene are described. The isomer 2 was shown to be identical with a sesquiterpene hydrocarbon isolated from oils of opoponax (Commiphora erythraea var. glabrescens Engler) and black pepper (Piper nigrum L.). The isomer 3 was found to be different from an isolate of Indian valerian oil (Valeriana wallichi) which has been assigned this structure. © 1969, American Chemical Society. All rights reserved.

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页码：4771 / &

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