REACTION OF ETHYLPEROXY RADICALS WITH NO2

被引:18
作者
ADACHI, H
BASCO, N
机构
[1] Department of Chemistry, University of British Columbia, Vancouver
基金
加拿大自然科学与工程研究理事会;
关键词
D O I
10.1016/0009-2614(79)85171-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The rate constant for the reaction C2H5O2+NO2 - products (10) has been measured directly by flash photolysis and kinetic spectroscopy in the pressure range 44-676 Torr. At room temperature k10=(7.5 ± 0.4) × 103 mole-1 s-1 so that the rate of formation of the probable primary product, peroxyethyl nitrate [(C2H5O2NO2) may be significant in urban atmospheres. © 1979.
引用
收藏
页码:324 / 328
页数:5
相关论文
共 24 条
[1]   KINETIC SPECTROSCOPY STUDY OF THE REACTION OF CH3O2 WITH NO [J].
ADACHI, H ;
BASCO, N .
CHEMICAL PHYSICS LETTERS, 1979, 63 (03) :490-492
[2]   KINETIC SPECTROSCOPY STUDY OF THE REACTION OF C2H5O2 WITH NO [J].
ADACHI, H ;
BASCO, N .
CHEMICAL PHYSICS LETTERS, 1979, 64 (03) :431-434
[3]  
ADACHI H, UNPUBLISHED
[4]   FLASH-PHOTOLYSIS STUDY OF SPECTRA OF CH3O2 AND C(CH3)3O2 RADICALS AND KINETICS OF THEIR MUTUAL REACTIONS AND WITH NO [J].
ANASTASI, C ;
SMITH, IWM .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 :1693-1701
[5]   RATES OF REACTION OF HO2 WITH HO AND O STUDIED BY LASER MAGNETIC-RESONANCE [J].
BURROWS, JP ;
HARRIS, GW ;
THRUSH, BA .
NATURE, 1977, 267 (5608) :233-234
[6]   COMPUTER MODELING OF SMOG CHAMBER DATA - PROGRESS IN VALIDATION OF A DETAILED MECHANISM FOR THE PHOTO-OXIDATION OF PROPENE AND NORMAL-BUTANE IN PHOTO-CHEMICAL SMOG [J].
CARTER, WPL ;
LLOYD, AC ;
SPRUNG, JL ;
PITTS, JN .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1979, 11 (01) :45-101
[7]   PHOTOOXIDATION OF METHANE IN PRESENCE OF NO AND NO2 [J].
COX, RA ;
DERWENT, RG ;
HOLT, PM ;
KERR, JA .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1976, 72 :2044-2060
[8]   KINETICS OF REACTION OF HO2 WITH NITRIC-OXIDE AND NITROGEN-DIOXIDE [J].
COX, RA ;
DERWENT, RG .
JOURNAL OF PHOTOCHEMISTRY, 1975, 4 (1-2) :139-153
[9]   SIGNIFICANCE OF PEROXYNITRIC ACID IN ATMOSPHERIC CHEMISTRY OF NITROGEN-OXIDES [J].
COX, RA ;
DERWENT, RG ;
HUTTON, AJL .
NATURE, 1977, 270 (5635) :328-329
[10]   PHOTOLYSIS OF NITROUS-ACID IN PRESENCE OF ACETALDEHYDE [J].
COX, RA ;
DERWENT, RG ;
HOLT, PM ;
KERR, JA .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1976, 72 :2061-2075