GENERALIZED STANDARD ADDITION METHOD

被引：281

作者：

SAXBERG, BEH ^{[1
]}

KOWALSKI, BR ^{[1
]}

机构：

[1] UNIV WASHINGTON,DEPT CHEM,CHEMOMETR LAB,SEATTLE,WA 98195

来源：

ANALYTICAL CHEMISTRY | 1979年 / 51卷 / 07期

关键词：

D O I：

10.1021/ac50043a059

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The normal standard addition method assumes that for any one anaiyte in a sample there is an analytical sensor which responds to that anaiyte and no other component in the sample. When the analytical sensor is not completely selective, so-called interference effects result which can be a major source of error. The generalized standard addition method (GSAM) provides a means of detecting interference effects, quantifying the magnitude of the interferences, and simultaneously determining anaiyte concentrations. The GSAM as presented here uses multiple linear regression to analyze multicomponent samples where the response-analyte concentration relationship is of some arbitrary polynomial form; for a nonlinear polynomial relationship, an iterative solution is required. © 1979, American Chemical Society. All rights reserved.

引用

页码：1031 / 1038

页数：8