STEREOSPECIFIC HYDROGENOLYSIS OF BENZYL-TYPE ALCOHOLS

被引：44

作者：

MITSUI, S

KUDO, Y

KOBAYASH.M

机构：

[1] Department of Applied Science, Faculty of Engineering, Tohoku University, Sendai

来源：

TETRAHEDRON | 1969年 / 25卷 / 09期

关键词：

D O I：

10.1016/S0040-4020(01)82813-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In order to obtain additional information regarding the stereospecificity of hydrogenolysis on Co and Cu as well as Ni and Pd, optically active methyl 3-hydroxy-3-phentybutyrate, 3-hydroxy-3-phenylvaleric acid, methyl 3-hydroxy-3-phenylvalerate and 3-phenylpentan-1,3-diol were hydrogenolysed. In the hydrogenolysis on Ni, Co and Cu, the configuration was retained whereas on Pd the inversion of configuration occurred as reported for other compounds. © 1969.

引用

页码：1921 / &

共 25 条

[1]

BREWSTER JH, 1964, CHEM IND-LONDON, P1759

[2] STERIC + OTHER INFLUENCES ON REACTIONS OF 6-+ 7-METHYLCHOLESTEROL DERIVATIVES [J].

CALLOW, RK ;

THOMPSON, GA .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (SEP) :3106-&

[3]

CRAM DJ, 1952, J AM CHEM SOC, V74, P149

[4] ON MECHANISM OF BENZYLIC SUBSTITUENT HYDROGENOLYSIS [J].

GARBISCH, EW ;

SCHREADE.L ;

FRANKEL, JJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (16) :4233-&

[5]

IIJIMA K, 1964, J CHEM SOC JAPAN PC, V85, P687

[6]

IMAIZUMI S, 1960, J CHEM SOC JAPAN PC, V81, P631

[7]

KHAN AM, 1966, TETRAHEDRON LETTERS, P2967

[8]

KONNO K, 1964, J CHEM SOC JAPAN PC, V85, P497

[9]

Levene PA, 1935, J BIOL CHEM, V110, P329

[10]

LEVENE PA, 1933, J BIO CHEM, V108, P409

← 1 2 3 →