CONVENIENT PREPARATION OF BINAP RUTHENIUM(II) COMPLEXES CATALYZING ASYMMETRIC HYDROGENATION OF FUNCTIONALIZED KETONES

被引：165

作者：

KITAMURA, M ^{[1
]}

TOKUNAGA, M ^{[1
]}

OHKUMA, T ^{[1
]}

NOYORI, R ^{[1
]}

机构：

[1] NAGOYA UNIV,DEPT CHEM,CHIKUSA KU,NAGOYA,AICHI 464,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(00)79892-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ligand exchange between [RuCl2(benzene)]2 or RuCl2[Sb(C6H5)3]3 and (R)- or (S)-BINAP produces BINAP-Ru(II) complexes which act as catalysts for the highly enantioselective hydrogenation of functionalized ketones.

引用

页码：4163 / 4166

页数：4

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