FTIR SPECTROSCOPIC MEASUREMENTS OF SURFACE BOND PRODUCTS OF NITROGEN-OXIDES ON AEROSOL SURFACES - IMPLICATIONS FOR HETEROGENEOUS HNO2 PRODUCTION

被引：49

作者：

JUNKERMANN, W ^{[1
]}

IBUSUKI, T ^{[1
]}

机构：

[1] NATL RES INST POLLUT & RESOURCES,TSUKUBA,IBARAKI 305,JAPAN

来源：

ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS | 1992年 / 26卷 / 17期

关键词：

HETEROGENEOUS REACTIONS; NITROGEN OXIDES; MARITIME AEROSOL;

D O I：

10.1016/0960-1686(92)90466-X

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

FTIR spectroscopy measurements have been made to investigate the products of heterogeneous reactions of nitrogen oxides like NO2, N2O5 and HNO2 in the presence of water vapour on artificial and natural aerosol surfaces. Surface species on NaCl particles differ significantly from those on urban aerosols or fly ash. Evidence for a nighttime production of NO2- on sea-salt surfaces from reactions of N2O5 and water vapour is given.

引用

页码：3099 / 3103

页数：5

共 20 条

[1] PHOTOENHANCEMENT OF THE NITROUS-ACID FORMATION IN THE SURFACE-REACTION OF NITROGEN-DIOXIDE AND WATER-VAPOR - EXTRA RADICAL SOURCE IN SMOG CHAMBER EXPERIMENTS [J].

AKIMOTO, H ;

TAKAGI, H ;

SAKAMAKI, F .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1987, 19 (06) :539-551

[2] THE EQUILIBRIUM-CONSTANT FOR N2O5-REVERSIBLE-NO2+NO-3 - ABSOLUTE DETERMINATION BY DIRECT MEASUREMENT FROM 243-K TO 397-K [J].

CANTRELL, CA ;

DAVIDSON, JA ;

MCDANIEL, AH ;

SHETTER, RE ;

CALVERT, JG .

JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (08) :4997-5006

[3] INFRARED-ABSORPTION CROSS-SECTIONS FOR N2O5 [J].

CANTRELL, CA ;

DAVIDSON, JA ;

MCDANIEL, AH ;

SHETTER, RE ;

CALVERT, JG .

CHEMICAL PHYSICS LETTERS, 1988, 148 (04) :358-362

[4] INFRARED STUDIES OF DISPROPORTIONATION REACTION OF NITRIC OXIDE ON Y-TYPE ZEOLITES [J].

CHAO, CC ;

LUNSFORD, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (01) :71-&

[5] INFRARED SPECTRA OF ISOTOPICALLY SUBSTITUTED NITRO- NITRITO- AND NITROSYL COMPLEXES [J].

CLEARE, MJ ;

GRIFFITH, WP .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (07) :1144-&

[6] POLLUTANT TRAPPING STUDIES .1. RESONANCE AND SPONTANEOUS RAMAN-SPECTRA OF THE DECOMPOSITION PRODUCTS OF NITROGEN-DIOXIDE ON OXIDE SURFACES [J].

COONEY, RP ;

TSAI, P .

JOURNAL OF RAMAN SPECTROSCOPY, 1980, 9 (01) :33-38

[7] THE NO3 RADICAL DECOMPOSITION AND NO3 SCAVENGING IN THE TROPOSPHERE [J].

DAVIDSON, JA ;

CANTRELL, CA ;

SHETTER, RE ;

MCDANIEL, AH ;

CALVERT, JG .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1990, 95 (D9) :13963-13969

[8] REACTION OF NO2 WITH NACL AND ATMOSPHERIC IMPLICATIONS OF NOCL FORMATION [J].

FINLAYSONPITTS, BJ .

NATURE, 1983, 306 (5944) :676-677

[9]

FINLAYSONPITTSB B, 1990, NATURE, V343, P662

[10] OBSERVATIONS OF NITROUS-ACID IN THE LOS-ANGELES ATMOSPHERE AND IMPLICATIONS FOR PREDICTIONS OF OZONE PRECURSOR RELATIONSHIPS [J].

HARRIS, GW ;

CARTER, WPL ;

WINER, AM ;

PITTS, JN ;

PLATT, U ;

PERNER, D .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1982, 16 (07) :414-419

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