DIRECT EVIDENCE FOR BROMINE OLEFIN CHARGE-TRANSFER COMPLEXES AS ESSENTIAL INTERMEDIATES OF THE FAST IONIC ADDITION OF BROMINE TO CYCLOHEXENE

被引：72

作者：

BELLUCCI, G ^{[1
]}

BIANCHINI, R ^{[1
]}

AMBROSETTI, R ^{[1
]}

机构：

[1] CNR,IST CHIM QUANTIST & ENERGET MOLEC,I-56100 PISA,ITALY

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1985年 / 107卷 / 08期

关键词：

D O I：

10.1021/ja00294a044

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：2464 / 2471

页数：8

共 35 条

[1] KINETICS AND MECHANISM OF THE REACTION OF CYCLOHEXENE WITH BROMINE IN THE PRESENCE OF PYRIDINE - COMPETITION BETWEEN DIFFERENT ELECTROPHILES [J].

BELLUCCI, G ;

BERTI, G ;

BIANCHINI, R ;

INGROSSO, G ;

AMBROSETTI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (25) :7480-7486

[2] COMPETING MECHANISTIC PATHWAYS IN THE BROMINATION OF 1,3-BUTADIENE WITH MOLECULAR BROMINE, PYRIDINE-BROMINE COMPLEX, AND TRIBROMIDE ION [J].

BELLUCCI, G ;

BERTI, G ;

BIANCHINI, R ;

INGROSSO, G ;

YATES, K .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (11) :2315-2323

[3] A KINETIC STUDY OF THE ADDITION OF BROMINE TO CROTONIC ACID IN ETHYLENE CHLORIDE [J].

BUCKLES, RE ;

YUK, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (20) :5048-5052

[4] KINETICS OF ADDITION OF BROMINE TO CIS- AND TRANS-STILBENE [J].

BUCKLES, RE ;

MILLER, JL ;

THURMAIE.RJ .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (04) :888-&

[5] THE REACTION OF BROMINE WITH CYCLOHEXENE IN CARBON-TETRACHLORIDE .1. REACTIONS IN THE ABSENCE OF HYDROGEN BROMIDE - PRESENCE OF A SCAVENGER [J].

BYRNELL, CJA ;

COOMBES, RG ;

HART, LS ;

WHITING, MC .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1983, (08) :1079-1086

[6]

de la Mare P. B. D., 1976, ELECTROPHILIC HALOGE

[7] KINETICS AND MECHANISMS OF ADDITIONS TO OLEFINIC SUBSTANCES .13. REACTIONS OF 3-SUBSTITUTED CHOLEST-5-ENES WITH SOURCES OF ELECTROPHILIC BROMINE [J].

DELAMARE, PBD ;

WILSON, RD .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1977, (15) :2048-2054

[8] THE KINETICS OF HALOGEN ADDITION TO UNSATURATED COMPOUNDS .7. BROMINE ADDITION IN CARBON TETRACHLORIDE, CHLOROBENZENE, AND CHLOROFORM [J].

DELAMARE, PBD ;

SCOTT, RA ;

ROBERTSON, PW .

JOURNAL OF THE CHEMICAL SOCIETY, 1945, :509-512

[9] COMPLEXES DE TRANSFERT DE CHARGE EVOLUTIFS OU CTCE ENTRE LE CHLORE LE BROME ET UNE SERIE DOLEFINES [J].

DUBOIS, JE ;

GARNIER, F .

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1967, A 23 (08) :2279-&

[10] ROLE OF TRANSITORY CHARGE-TRANSFER COMPLEXES IN BROMINATION OF OLEFINS [J].

DUBOIS, JE ;

GARNIER, F .

CHEMICAL COMMUNICATIONS, 1968, (05) :241-&

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