SN2-SN1 SPECTRUM .1. ROLE OF NUCLEOPHILIC SOLVENT ASSISTANCE AND NUCLEOPHILICALLY SOLVATED ION-PAIR INTERMEDIATES IN SOLVOLYSES OF PRIMARY AND SECONDARY ARENESULFONATES

被引：262

作者：

BENTLEY, TW

SCHLEYER, PV

机构：

[1] UNIV COLL SWANSEA, DEPT CHEM, SWANSEA SA2 8PP, WALES

[2] PRINCETON UNIV, DEPT CHEM, PRINCETON, NJ 08540 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1976年 / 98卷 / 24期

关键词：

D O I：

10.1021/ja00440a036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：7658 / 7666

页数：9

共 143 条

[1] SUBSTITUTION AT SATURATED CARBON .12. CALCULATION OF ELECTROSTATIC CONTRIBUTION TO FREE ENERGIES OF TRANSFER FROM METHANOL TO AQUEOUS METHANOL AND TO WATER OF SOLUTES AND TRANSITION STATES - NEW METHOD FOR EXAMINATION OF TRANSITION STATES [J].

ABRAHAM, MH ;

JOHNSTON, GF .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (10) :1610-&

[2] THERMODYNAMIC PARAMETERS FOR IONIZATION AND DISSOCIATION OF ALKYL-HALIDES IN WATER AND NON-AQUEOUS SOLVENTS - COMMENTS ON ION-PAIR MECHANISM OF NUCLEOPHILIC-SUBSTITUTION [J].

ABRAHAM, MH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1973, (14) :1893-1899

[3] EVIDENCE AGAINST APPRECIABLE HIDDEN RETURN IN SOLVOLYSES OF SIMPLE SECONDARY SUBSTRATES [J].

BENTLEY, TW ;

LIGGERO, SH ;

IMHOFF, MA ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (06) :1970-1973

[4] CORRELATION OF SOLVOLYSIS RATES WITH 3-PARAMETER AND 4-PARAMETER RELATIONSHIPS - SCALE OF SOLVENT NUCLEOPHILICITIES [J].

BENTLEY, TW ;

SCHADT, FL ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (03) :992-&

[5]

BENTLEY TW, 1976, ADV PHYS ORG CHEM, V14, P1

[6] MECHANISM OF SUBSTITUTION AT A SATURATED CARBON ATOM .36. UNIMOLECULAR MENSCHUTKIN REACTIONS IN SULPHUR DIOXIDE SOLUTION REMARKS ON THE THEORY OF BORDER-LINE MECHANISMS [J].

BIRD, ML ;

HUGHES, ED ;

INGOLD, CK .

JOURNAL OF THE CHEMICAL SOCIETY, 1954, (FEB) :634-642

[7] CLASSICAL CARBONIUM-IONS .5. STEREOCHEMISTRY OF SUBSTITUTION IN SOLVOLYSIS OF 2-ADAMANTYL AND 2-METHYL-2-ADAMANTYL DERIVATIVES [J].

BONE, JA ;

PRITT, JR ;

WHITING, MC .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1975, (13) :1447-1452

[8]

BONE JA, 1970, CHEM COMMUN, P115

[9] MODE OF SOLVENT PARTICIPATION IN SOLVOLYSIS REACTIONS AT A TERTIARY CARBON-ATOM [J].

BORDWELL, FG ;

WILEY, PF ;

MECCA, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (01) :132-136

[10] FORMATION OF AN ION-PAIR INTERMEDIATE IN AN SN2-TYPE REACTION [J].

BORDWELL, FG ;

MECCA, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (01) :123-127

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