Dissociative adsorption of HCOOH, CH3OH, and CH2O on MCM-41

被引：34

作者：

Chen, MT ^{[1
]}

Lin, YS ^{[1
]}

Lin, YF ^{[1
]}

Lin, HP ^{[1
]}

Lin, JL ^{[1
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem, Tainan 701, Taiwan

来源：

JOURNAL OF CATALYSIS | 2004年 / 228卷 / 01期

关键词：

HCOOH; CH3OH; CH2O; adsorption; MCM-41;

D O I：

10.1016/j.jcat.2004.08.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Adsorption and surface reactions of HCOOH, CH3OH, and CH2O on siliceous mesoporous MCM-41 have been investigated by Fouriertransform infrared spectroscopy. CH2O decomposes on the surface to form adsorbed CH3O and HCOO (an analog of Cannizzaro disproportionation) which are identified by dissociative adsorption of CH3OH and HCOOH. In addition, CH3OH is sequentially oxidized to CH2O and HCOO on MCM-41. These types of reactions for CH2O and CH3OH on MCM-41 have not been observed on amorphous SiO2 without a mesoporous structure. (C) 2004 Elsevier Inc. All rights reserved.

引用

收藏

页码：259 / 263

页数：5

相关论文

共 34 条

[1] Surface characterization and functionalization of MCM-41 silicas via silazane silylation [J].

Anwander, R ;

Nagl, I ;

Widenmeyer, M ;

Engelhardt, G ;

Groeger, O ;

Palm, C ;

Röser, T .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (15) :3532-3544

[2] SILICA AS AN OXIDATION CATALYST [J].

ARMOR, JN ;

ZAMBRI, PM .

JOURNAL OF CATALYSIS, 1982, 73 (01) :57-65

[3] WIDE TEMPERATURE-RANGE IR SPECTROSCOPY CELL FOR STUDIES OF ADSORPTION AND DESORPTION ON HIGH AREA SOLIDS [J].

BASU, P ;

BALLINGER, TH ;

YATES, JT .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1988, 59 (08) :1321-1327

[4] THERMAL-ACTIVATION OF SILICA AT TEMPERATURES BELOW 500-DEGREES-C [J].

BITTNER, EW ;

BOCKRATH, BC ;

SOLAR, JM .

JOURNAL OF CATALYSIS, 1994, 149 (01) :206-210

[5]

BOEHM HP, 1983, CATALYSIS SCI TECHNO, V4, pCH2

[6]

BRUICE PY, 1998, ORGANIC CHEM, P856

[7] Functionalized micelle-templated silicas (MTS) and their use as catalysts for fine chemicals [J].

Brunel, D .

MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 27 (2-3) :329-344

[8] FT-IR STUDY OF THE ADSORPTION AND TRANSFORMATION OF FORMALDEHYDE ON OXIDE SURFACES [J].

BUSCA, G ;

LAMOTTE, J ;

LAVALLEY, JC ;

LORENZELLI, V .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (17) :5197-5202

[9] Heterogeneous uptake kinetics of volatile organic compounds on oxide surfaces using a Knudsen cell reactor:: Adsorption of acetic acid, formaldehyde, and methanol on α-Fe2O3, α-Al2O3, and SiO2 [J].

Carlos-Cuellar, S ;

Li, P ;

Christensen, AP ;

Krueger, BJ ;

Burrichter, C ;

Grassian, VH .

JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (21) :4250-4261

[10] FTIR study of adsorption and reactions of methyl formate on powdered TiO2 [J].

Chuang, CC ;

Wu, WC ;

Huang, MC ;

Huang, IC ;

Lin, JL .

JOURNAL OF CATALYSIS, 1999, 185 (02) :423-434

← 1 2 3 4 →