Three-dimensional self-assembly of gold nanocolloids in spheroids due to dialysis in the presence of sodium mercaptoacetate

被引：28

作者：

Adachi, E ^{[1
]}

机构：

[1] LOreal Tsukuba Ctr, Tsukuba, Ibaraki 3002635, Japan

来源：

LANGMUIR | 2000年 / 16卷 / 16期

关键词：

D O I：

10.1021/la000244x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Elemental gold nanocolloids were synthesized by reducing an aurate aqueous solution in the presence of sodium mercaptoacetate. The nanocolloids, 4.6 nm in diameter, self-assembled in highly monodispersed spherical aggregates, 30 nm in diameter, when the nanocolloid suspension was dialyzed in water. Elimination of excess ions, due to dialysis, caused the three-dimensional self-assembly of the nanocolloids. The spheroid and also the elemental nanocolloids before dialysis did not produce the plasmonic absorption peak that is characteristic of conventional gold colloids. Chemisorption of mercaptoacetate onto the nanocolloids caused the peak to disappear. The features of the spheroid structure and assembly mechanism are presented.

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页码：6460 / 6463

页数：4

相关论文

共 23 条

[1] Self-assembly of a two-dimensional superlattice of molecularly linked metal clusters [J].

Andres, RP ;

Bielefeld, JD ;

Henderson, JI ;

Janes, DB ;

Kolagunta, VR ;

Kubiak, CP ;

Mahoney, WJ ;

Osifchin, RG .

SCIENCE, 1996, 273 (5282) :1690-1693

[2] SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].

BRUST, M ;

WALKER, M ;

BETHELL, D ;

SCHIFFRIN, DJ ;

WHYMAN, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802

[3] Reversible tuning of silver quantum dot monolayers through the metal-insulator transition [J].

Collier, CP ;

Saykally, RJ ;

Shiang, JJ ;

Henrichs, SE ;

Heath, JR .

SCIENCE, 1997, 277 (5334) :1978-1981

[4] THE PHYSICS OF SIMPLE METAL-CLUSTERS - EXPERIMENTAL ASPECTS AND SIMPLE-MODELS [J].

DEHEER, WA .

REVIEWS OF MODERN PHYSICS, 1993, 65 (03) :611-676

[5]

DEVORET MH, 1992, NATO ADV SCI I B-PHY, V294, P1

[6] LOW-TEMPERATURE SPECIFIC-HEAT OF THE CLUSTER COMPOUND AU55(P(C6H5)3)12CL6 [J].

GOLL, G ;

VONLOHNEYSEN, H ;

KREIBIG, U ;

SCHMID, G .

ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1991, 20 (1-4) :329-331

[7] Colloids - A surprisingly attractive couple [J].

Grier, DG .

NATURE, 1998, 393 (6686) :621-+

[8] ELECTRICAL DOUBLE-LAYER FORCES - A MONTE-CARLO STUDY [J].

GULDBRAND, L ;

JONSSON, B ;

WENNERSTROM, H ;

LINSE, P .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (05) :2221-2228

[9] THE OPTICAL KERR EFFECT IN SMALL METAL PARTICLES AND METAL COLLOIDS - THE CASE OF GOLD [J].

HACHE, F ;

RICARD, D ;

FLYTZANIS, C ;

KREIBIG, U .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1988, 47 (04) :347-357

[10] OPTICAL NONLINEARITIES OF SMALL METAL PARTICLES - SURFACE-MEDIATED RESONANCE AND QUANTUM SIZE EFFECTS [J].

HACHE, F ;

RICARD, D ;

FLYTZANIS, C .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1986, 3 (12) :1647-1655