Adsorption studies on Citrus reticulata (fruit peel of orange):: removal and recovery of Ni(II) from electroplating wastewater

被引:400
作者
Ajmal, M [1 ]
Rao, RAK [1 ]
Ahmad, R [1 ]
Ahmad, J [1 ]
机构
[1] Aligarh Muslim Univ, Fac Engn & Technol, Dept Appl Chem, Environm Res Lab, Aligarh 202002, Uttar Pradesh, India
关键词
endothermic; adsorption; isotherm; desorption; regeneration;
D O I
10.1016/S0304-3894(00)00234-X
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The ability of fruit peel of orange to remove Zn, Ni, Cu, Pb and Cr from aqueous solution by adsorption was studied. The adsorption was in the order of Ni(II) > Cu(II) > Pb(II) > Zn(II) > Cr(II). The extent of removal of NI(II) was found to be dependent on sorbent dose, initial concentration, pH and temperature. The adsorption follows first-order kinetics. The process is endothermic showing monolayer adsorption of Ni(II), with a maximum adsorption of 96% at 50 degreesC for an initial concentration of 50 mg l(-1) at pH 6. Thermodynamic parameters were also evaluated. Desorption was possible with 0.05 M HCl and was found to be 95.83% in column and 76% in batch process, respectively. The spent adsorbent was regenerated and recycled thrice. The removal and recovery was also done in wastewater and was found to be 89% and 93.33%, respectively. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:117 / 131
页数:15
相关论文
共 37 条
[1]   Studies on removal and recovery of Cr(VI) from electroplating wastes [J].
Ajmal, M ;
Rao, RAK ;
Siddiqui, BA .
WATER RESEARCH, 1996, 30 (06) :1478-1482
[2]  
Ajmal Mohammad, 1998, Indian Journal of Environmental Health, V40, P15
[3]   THERMODYNAMIC STUDY ON THE EFFECTS OF BETA-CYCLODEXTRIN INCLUSION WITH ANILINONAPHTHALENESULFONATES [J].
CATENA, GC ;
BRIGHT, FV .
ANALYTICAL CHEMISTRY, 1989, 61 (08) :905-909
[4]   STUDY ON THE ADSORPTION CAPACITY OF THE SYSTEM CLAYCARBON FOR WATER-TREATMENT [J].
DONATI, A ;
SIETZ, M ;
MORSELLI, L ;
ZAPPOLI, S ;
GHEDUZZI, A .
TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY, 1992, 35 (1-2) :87-92
[5]   ADSORPTION CHARACTERISTICS OF SOME CU(II) COMPLEXES ON ALUMINOSILICATES [J].
ELLIOTT, HA ;
HUANG, CP .
WATER RESEARCH, 1981, 15 (07) :849-855
[6]   THE SPECIATION OF TRACE-ELEMENTS IN WATERS [J].
FLORENCE, TM .
TALANTA, 1982, 29 (05) :345-364
[7]  
Forstner U, 1981, METAL POLLUTION AQUA
[8]  
Fraiji L.K., 1992, J CHEM EDUC, V69, P205
[9]  
FRIBERG L, 1980, CADMIUM ENV
[10]   MERCURY UPTAKE BY SELECTED AGRICULTURAL PRODUCTS AND BY-PRODUCTS [J].
FRIEDMAN, M ;
WAISS, AC .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1972, 6 (05) :457-&