Thiacalixarenes:: Synthesis and structural analysis of thiacalix[4]arene and of p-tert-butylthiacalix[4]arene

被引：201

作者：

Akdas, H

Bringel, L

Graf, E

Hosseini, MW

Mislin, G

Pansanel, J

De Cian, A

Fischer, J

机构：

[1] Univ Strasbourg 1, Inst Le Bel, CNRS, Chim Coordinat Organ Lab, F-67000 Strasbourg, France

[2] Univ Strasbourg 1, Inst Le Bel, CNRS, Lab Cristallochim & Chim Struct, F-67000 Strasbourg, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 16期

关键词：

D O I：

10.1016/S0040-4039(98)00067-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of tetrathiacalix[4]arene was achieved by the detertiobutylation of p-tert-butyltetrathiacalix[4]arene. X-ray diffraction studies revealed that in the solid state whereas p-tert-butyltetrathiacalix[4]arene forms inclusion complexes with solvent molecules, tetrathiacalix[4]arene undergoes self-inclusion leading to trimeric units. The same behaviour in the crystalline phase was also demonstrated for calix[4]arene. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

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页码：2311 / 2314

页数：4

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