Raman spectrum of graphene and graphene layers

被引：14272

作者：

Ferrari, A. C.

Meyer, J. C.

Scardaci, V.

Casiraghi, C.

Lazzeri, M.

Mauri, F.

Piscanec, S.

Jiang, D.

Novoselov, K. S.

Roth, S.

Geim, A. K.

机构：

[1] Univ Cambridge, Dept Engn, Cambridge CB3 0FA, England

[2] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany

[3] Univ Paris 06, IMPMC, F-75015 Paris, France

[4] Univ Paris 07, CNRS, IPGP, F-75015 Paris, France

[5] Univ Manchester, Dept Phys & Astron, Manchester M13 9PL, Lancs, England

来源：

PHYSICAL REVIEW LETTERS | 2006年 / 97卷 / 18期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1103/PhysRevLett.97.187401

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Graphene is the two-dimensional building block for carbon allotropes of every other dimensionality. We show that its electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers. The D peak second order changes in shape, width, and position for an increasing number of layers, reflecting the change in the electron bands via a double resonant Raman process. The G peak slightly down-shifts. This allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area.

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页数：4

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共 30 条

[1] Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics [J].

Berger, C ;

Song, ZM ;

Li, TB ;

Li, XB ;

Ogbazghi, AY ;

Feng, R ;

Dai, ZT ;

Marchenkov, AN ;

Conrad, EH ;

First, PN ;

de Heer, WA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (52) :19912-19916

[2] Coulomb oscillations and Hall effect in quasi-2D graphite quantum dots [J].

Bunch, JS ;

Yaish, Y ;

Brink, M ;

Bolotin, K ;

McEuen, PL .

NANO LETTERS, 2005, 5 (02) :287-290

[3] Anisotropy of the Raman spectra of nanographite ribbons -: art. no. 047403 [J].

Cançado, LG ;

Pimenta, MA ;

Neves, BRA ;

Medeiros-Ribeiro, G ;

Enoki, T ;

Kobayashi, Y ;

Takai, K ;

Fukui, K ;

Dresselhaus, MS ;

Saito, R ;

Jorio, A .

PHYSICAL REVIEW LETTERS, 2004, 93 (04) :047403-1

[4] Stokes and anti-Stokes double resonance Raman scattering in two-dimensional graphite -: art. no. 035415 [J].

Cançado, LG ;

Pimenta, MA ;

Saito, R ;

Jorio, A ;

Ladeira, LO ;

Grueneis, A ;

Souza, AG ;

Dresselhaus, G ;

Dresselhaus, MS .

PHYSICAL REVIEW B, 2002, 66 (03) :354151-354155

[5] Interpretation of Raman spectra of disordered and amorphous carbon [J].

Ferrari, AC ;

Robertson, J .

PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107

[6] Raman spectroscopy in carbons: from nanotubes to diamond - Preface [J].

Ferrari, AC ;

Robertson, J .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2004, 362 (1824) :2269-2270

[7] Linewidth of the Raman features of individual single-wall carbon nanotubes -: art. no. 115411 [J].

Jorio, A ;

Fantini, C ;

Dantas, MSS ;

Pimenta, MA ;

Souza, AG ;

Samsonidze, GG ;

Brar, VW ;

Dresselhaus, G ;

Dresselhaus, MS ;

Swan, AK ;

Ünlü, MS ;

Goldberg, BB ;

Saito, R .

PHYSICAL REVIEW B, 2002, 66 (11) :1154111-1154118

[8] Double resonant Raman phenomena enhanced by van Hove singularities in single-wall carbon nanotubes -: art. no. 165433 [J].

Kürti, J ;

Zólyomi, V ;

Grüneis, A ;

Kuzmany, H .

PHYSICAL REVIEW B, 2002, 65 (16) :1654331-1654339

[9] CHARACTERIZATION OF CARBON MATERIALS WITH RAMAN MICROSPECTROMETRY [J].

LESPADE, P ;

MARCHAND, A ;

COUZI, M ;

CRUEGE, F .

CARBON, 1984, 22 (4-5) :375-385

[10] Double-resonant Raman scattering in graphite: Interference effects, selection rules, and phonon dispersion [J].

Maultzsch, J ;

Reich, S ;

Thomsen, C .

PHYSICAL REVIEW B, 2004, 70 (15) :155403-1