Superparamagnetic high-magnetization microspheres with an Fe3O4@SiO2 core and perpendicularly aligned mesoporous SiO2 shell for removal of microcystins

被引:1600
作者
Deng, Yonghui [1 ,2 ]
Qi, Dawei [1 ,2 ]
Deng, Chunhui [1 ,2 ]
Zhang, Xiangmin [1 ,2 ]
Zhao, Dongyuan [1 ,2 ]
机构
[1] Fudan Univ, Shanghai Key Lab Mol Catalysis, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China
关键词
D O I
10.1021/ja0777584
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Superparamagnetic microspheres with an Fe3O4@SiO2 core and a perpendiculary aligned mesoporous SiO2 shell were synthesized through a surfactant-templating solgel approach. The microspheres possess high magnetization (53.3 emu/g), high surface area (365 m(2)/g), large pore volume (0.29 cm(3)/g), and uniform mesopore (2.3 nm). By using the unique core-shell microspheres with accessible large pores and excellent magnetic property, a fast removal of microcystins with high efficiency (> 95%) can be achieved.
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页码:28 / +
页数:3
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