Reversible binding of dioxygen by a non-transition-metal complex

被引：119

作者：

Abakumov, GA ^{[1
]}

Poddel'sky, AI ^{[1
]}

Grunova, EV ^{[1
]}

Cherkasov, VK ^{[1
]}

Fukin, GK ^{[1
]}

Kurskii, YA ^{[1
]}

Abakumova, LG ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 18期

关键词：

antimony; N; O ligands; oxo ligands; oxygen; peroxides;

D O I：

10.1002/anie.200462503

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dioxygen binds reversibly to the non-transition-metal complex 1 to form the spiroendoperoxide 2 (see scheme). Complexes 1 and 2 were characterized by NMR, IR, and UV/Vis spectroscopies, and their molecular structures were determined by X-ray crystallography. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2767 / 2771

页数：5

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