Efficient catalysis of a Diels-Alder reaction by metallo-vesicles in aqueous solution

被引：67

作者：

Rispens, T ^{[1
]}

Engberts, JBFN ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst, Phys Organ Chem Unit, NL-9747 AG Groningen, Netherlands

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 06期

关键词：

D O I：

10.1021/ol015611q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Vesicles have been prepared from a cyclic phosphate ester (5,5-di-n-dodecyl-2-hydroxy-1,3,2-dioxaphosphorinan-2-one) with copper(ll) counterions (Cu(dDP)(2)). They form a highly efficient aqueous Lewis acid catalyst system. The reaction of two azachalcon derivatives (la, Ib) with cyclopentadiene (2) was studied to elucidate the catalytic potential of this system.

引用

页码：941 / 943

页数：3

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