Cathodes for lithium-ion batteries: Some comparisons

被引:32
作者
Goodenough, JB [1 ]
Manivannan, V [1 ]
机构
[1] Univ Texas, Texas Mat Inst, Austin, TX 78712 USA
来源
DENKI KAGAKU | 1998年 / 66卷 / 12期
关键词
NASICONs; brannerites; oxospinels; olivines;
D O I
10.5796/kogyobutsurikagaku.66.1173
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Following a review of quality criteria for the design of a cathode insertion host for a lithium-ion rechargeable battery, comparisons are made between layered and framework hosts having simple anion versus polyanion arrays. The electrochemical performance of the brannerite Li1+x VMoO6 is shown to support a larger capacity (200 mAh/g), but a lower voltage (2.4 V vs lithium), than the NASICON system Li1+xFe2(SO4)(2)PO4 (80 mAh/g at 3.3 V) at a current density of 1 mA/cm(2).
引用
收藏
页码:1173 / 1181
页数:9
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