Rheology and aging: A simple approach

被引:106
作者
Derec, C
Ajdari, A
Lequeux, F
机构
[1] Ecole Super Phys & Chim Ind Ville Paris, CNRS, Esa 7083, Lab Physicochim Macromol, F-75231 Paris 05, France
[2] Ecole Super Phys & Chim Ind Ville Paris, CNRS, UMR 7615, Lab Physicochim Macromol, F-75231 Paris 05, France
关键词
D O I
10.1007/s101890170118
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We introduce a rheological model to describe the low-frequency mechanical properties of systems near a fluid/paste transition. We propose a Landau-like expansion for the vicinity of this transition, treating the stress relaxation rate as an order parameter. This leads to a formally simple model that allows us to describe the interplay between aging and non-linearities in the mechanical response of the system. We focus here on systems prepared bq. fluidification under a strong shear, on which mechanical measurements are performed (oscillatory rheology, stress relaxation: response to a steady sheer rate), after a waiting time during which the system evolves on its own.
引用
收藏
页码:355 / 361
页数:7
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