Box-Behnken design: An alternative for the optimization of analytical methods

被引：2561

作者：

Ferreira, S. L. C. ^{[1
]}

Bruns, R. E.

Ferreira, H. S.

Matos, G. D.

David, J. M.

Brandao, G. C.

da Silva, E. G. P.

Portugal, L. A.

dos Reis, P. S.

Souza, A. S.

dos Santos, W. N. L.

机构：

[1] Univ Fed Bahia, Inst Quim, Campus Univ Ondina, BR-40170290 Salvador, BA, Brazil

[2] Univ Estadual Campinas, Inst Quim, BR-13084971 Sao Paulo, Brazil

[3] Univ Do Estado Bahia, BR-41195001 Salvador, BA, Brazil

来源：

ANALYTICA CHIMICA ACTA | 2007年 / 597卷 / 02期

关键词：

Box-Behnken design : multivariate optimization; experimental design; analytical methods; desirability function; robustness; ONLINE PRECONCENTRATION SYSTEM; ATOMIC-ABSORPTION-SPECTROMETRY; LIQUID-LIQUID-EXTRACTION; SOLID-PHASE EXTRACTION; CLOUD POINT EXTRACTION; FACTORIAL-DESIGN; MULTIVARIATE OPTIMIZATION; GAS-CHROMATOGRAPHY; DOEHLERT MATRIX; LEAD DETERMINATION;

D O I：

10.1016/j.aca.2007.07.011

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The present paper describes fundamentals, advantages and limitations of the Box-Behnken design (BBD) for the optimization of analytical methods. It establishes also a comparison between this design and composite central, three-level full factorial and Doehlert designs. A detailed study on factors and responses involved during the optimization of analytical systems is also presented. Functions developed for calculation of multiple responses are discussed, including the desirability function, which was proposed by Derringer and Suich in 1980. Concept and evaluation of robustness of analytical methods are also discussed. Finally, descriptions of applications of this technique for optimization of analytical methods are presented. (C) 2007 Elsevier B.V.. All rights reserved.

引用

页码：179 / 186

页数：8

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