Metallic resistivity in crystalline ropes of single-wall carbon nanotubes

被引:369
作者
Fischer, JE
Dai, H
Thess, A
Lee, R
Hanjani, NM
Dehaas, DL
Smalley, RE
机构
[1] UNIV PENN, RES STRUCT MATTER LAB, PHILADELPHIA, PA 19104 USA
[2] RICE UNIV, RICE QUANTUM INST, CTR NANOSCALE SCI & TECHNOL, HOUSTON, TX 77251 USA
[3] RICE UNIV, DEPT CHEM, HOUSTON, TX 77251 USA
[4] RICE UNIV, DEPT PHYS, HOUSTON, TX 77251 USA
关键词
D O I
10.1103/PhysRevB.55.R4921
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Laser ablation of (Co,Ni)-doped graphite yields similar to 70% single-wall nanotubes, predominantly (10,10) armchair tubes which self-organize into crystalline ''ropes''>100 Angstrom in diameter and>10 mu m long. We find rho(parallel to)=0.03-0.10 m Omega cm at 300 K, with positive (negative) d rho/dT above (below) T* = 35 K. Unoriented bulk samples exhibit similar behavior, with higher (directionally averaged) resistivities and T*'s. The high-T behavior is consistent with the predicted intrinsic metallic state for this structure.
引用
收藏
页码:R4921 / R4924
页数:4
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