MECHANISM OF CHEMILUMINESCENCE FROM PEROXY RADICALS

被引：96

作者：

KELLOGG, RE

机构：

[1] Central Research Department, Experimental Station, E. I. du Pont de Nemours and Company, Wilmington

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 20期

关键词：

D O I：

10.1021/ja01048a005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemiluminescence accompanying disproportionation of peroxy radicals is studied. This reaction produces triplet states specifically (T/S > 104) and with high efficiency. The low emission yield, Φc ≅ 10−8-10−10 is ascribed to quenching in the cage by the eliminated O2. © 1969, American Chemical Society. All rights reserved.

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页码：5433 / &

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