ELECTRONIC FACTORS GOVERNING THE RELATIVE STABILITIES OF GEOMETRIC ISOMERS OF OCTAHEDRAL COMPLEXES WITH PI-ACCEPTOR AND PI-DONOR LIGANDS

被引：104

作者：

MINGOS, DMP

机构：

[1] Inorganic Chemistry Laboratory, University of Oxford, Oxford, OXI 3QR, South Parks Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 179卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)95229-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Extended Hückel molecular orbital calculations have shown that the relative stabilities of geometric isomers in 16, 17 and 18 electron octahedral complexes containing strong π-acid or π-donor ligands depend on the number of valence electrons and in a complementary Fashion on whether the ligands are π-donors or π-acceptors. © 1979.

引用

页码：C29 / C33

页数：5

共 6 条

[1] CHARACTERIZATION AND ELECTROCHEMICAL BEHAVIOR OF GROUP VI DICARBONYLBIS(DIPHENYLPHOSPHINO)METHANE COMPLEXES [J].