DERIVATIVES OF METHYLENEDIOXY-BENZENE .24. SYNTHESIS OF O-SAFROLE AND OF MYRISTICINE

被引：7

作者：

DALLACKE.F

SLUYSMAN.R

机构：

[1] Institut für Organische Chemie der Technischen Hochschule Aachen, Aachen

来源：

MONATSHEFTE FUR CHEMIE | 1969年 / 100卷 / 02期

关键词：

D O I：

10.1007/BF00904102

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Preparation of 2.3-methylenedioxy-allylbenzene (o-safrole) (1 d) free of isomers by reaction of 2.3-dihydroxy-allylbenzene (1 b) with CH2BrCl is described. Treating 4-hydroxy-3-methoxy-allylbenzene (3 a) with potassium nitrosodisulfonate gives 3-methoxy-5-allyl-o-benzoquinone (4) which ist reduced to 3-methoxy-5-allyl-pyrocatechol (5) with sodium dithionite. Methylenation of 3 c gives myristicin with good yield. © 1969 Springer-Verlag.

引用

页码：560 / &

共 9 条

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