SELF-ASSEMBLY OF HYDROPHOBIZED POLYSACCHARIDE - STRUCTURE OF HYDROGEL NANOPARTICLE AND COMPLEXATION WITH ORGANIC-COMPOUNDS

被引：24

作者：

AKIYOSHI, K

DEGUCHI, S

TAJIMA, H

NISHIKAWA, T

SUNAMOTO, J

机构：

[1] Division of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-01, Sakyo-ku, Yoshida Hommachi

来源：

PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES | 1995年 / 71卷 / 01期

关键词：

SELF-ASSEMBLY; POLYMER AMPHIPHILE; NANOPARTICLE; HYDROGEL; HYDROPHOBIZED POLYSACCHARIDE; ENANTIOSELECTIVITY; BILIRUBIN;

D O I：

10.2183/pjab.71.15

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Self-assembly of hydrophobized polysaccharides in water was investigated by dynamic and static light scatterings, and by fluorescence and circular dichroism spectroscopies. Cholesterol-bearing pullulan (CHP) forms nanosize hydrogel by self-aggregation in water. The hydrogel network was formed by non-covalent cross-linked domain. The nanoparticles strongly bound various hydrophobic compounds. Induced circular dichroism was observed upon the enantioselective binding with bilirubin.

引用

页码：15 / 19

页数：5

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